![]() molecular characterisation techniques of (emulsion) polymers is given whereas in Chapter 8 the characterisation techniques available for particle size, shape and morphology are reviewed In Chapters 9 and 10, bulk and specialty applications are discussed We hope that this book will become a standard textbook in courses in emulsion polymerisation Chemistry and Technology ofEmulsion Polymerisation Edited by. and Dale, 1945) and Price and Adams (Price and Adams, 1945), on the influence of catalyst concentration on the initial rate of polymerisation and Montroll (Montroll, 1945) developed a general phenomenological theory of processes during which diffusion and chemical reaction cooperate in the formation of large molecules A large amount of basic research was carried out on all phases of emulsion polymerisation. 1942, McBain and Soldate, 1944) was very likely to be the most 5 6 Chemistry and Technology ofEmulsion Polymerisation important site for initiation of polymerisation Hohenstein, Mark, Siggia, and Vingiello (Hohenstein, 1945, Hohenstein et al., 1944a, Hohenstein et al., 1944b) studied the polymerisation of styrene in aqueous solutions without soap and in aqueous emulsions in the presence of soap At the. ![]() occupation with emulsion polymerisation (and also that of the present author) We see from the citation above that Mark and Hohenstein mention the monomers styrene, dichlorostyrene, isoprene, vinyl acetate and acrylonitrile After the invention of emulsion polymerisation, many monomers were investigated, but not all of these were of commercial interest Further development of emulsion polymerisation of vinyl. both in the monomer droplets and the soap micelles, the case is intermediate between suspension and emulsion polymerisation There also exist emulsion 7 8 Chemistry and Technology ofEmulsion Polymerisation polymerisations (vinyl acetate, acrylonitrile) in which the monomer is substantially soluble in water and a reaction which is a superposition of solution, suspension, and emulsion polymerisation is. historic overview of the understanding of emulsion polymerisation, while also focusing on the solution of the 2 Chemistry and Technology ofEmulsion Polymerisation kinetic equations In Chapter 2 an introduction is given in the radical (co)polymerisation mechanism, explaining kinetics and the development of molecular weight and chemical composition In Chapter 3, the basic elements of emulsion polymerisation. These latest developments are included in the second edition. Controlled radical polymerisation is used in aiding encapsulation of inorganic particles like pigment particles and clay platelets. The second edition of this book includes a new chapter on morphology of latex particles, a rapidly progressing area where modelling the thermodynamic and kinetic aspects of phase separation and morphology has developed into a mature and powerful tool to predict and control morphology of latex particles.Īnother area that is rapidly progressing is the application of controlled radical polymerisation in emulsion polymerization. By carefully explaining the principles of the reaction, based on well-designed experimental investigation, the book explains how the principles relate to practical application. For those working in industry, coupling theory with everyday practice can be difficult. Chemistry and Technology of Emulsion Polymerisation 2e provides a practical and intuitive explanation of emulsion polymerization, in combination with both conventional and controlled radical polymerization.
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